Ceramic Machining: Types, Methods and Applications
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Introduction
This article will take an in-depth look at ceramic machining.
The article will bring more detail on topics such as:
Principles of Ceramic Machining
Types and Methods of Ceramic Machining
Categories and Types of Ceramics
Advantages, Disadvantages and Applications of Ceramics in Ceramic Machining
And Much More…
Chapter 1: What Are The Principles of Ceramic Machining
This chapter will discuss what ceramic machining is, how it is performed, and other considerations regarding ceramic machining.
What is Ceramic Machining?
Ceramic machining refers to a series of processes used to cut and shape ceramic materials to meet precise tolerances for a part. This includes milling, drilling, grinding, and turning the ceramic workpiece. Ceramic machining can occur at two stages in the manufacturing process: green body machining, which is performed on the unfired ceramic material, and full density machining, which is done after the ceramic has been fired and fully densified.
Green body ceramic machining is performed after a ceramic part has undergone bisque firing but before it has been fired to full density. This stage can be accomplished with steel and conventional tools. In contrast, full density machining, which occurs after the ceramic has been fully fired, is more challenging and requires specialized tools. These tools must be durable enough to handle the hard, dense material and typically include diamond cutters.
Ceramic machining, similar to metal machining, involves a material removal process that demands precise control and monitoring. This technique is employed to achieve tight tolerances and create detailed features for surface finishes and diameter dimensions. When working with green ceramics, the machining process uses standard methods, as the material has not yet been hardened.
Ceramic products, parts, and components are characterized by their hardness, brittleness, heat and corrosion resistance, high strength, low density, and high stiffness. They also exhibit wear resistance and thermal stability. Ceramics are created by shaping and firing nonmetallic minerals, such as clay, at elevated temperatures.
Why Ceramics Have to be Machined
For fired ceramics, machining is required to achieve precise tolerances that cannot be met during green ceramic machining. While green ceramics can achieve some tolerances, aspects such as hole diameters and surface finishes often need additional machining after firing. Special features on ceramic tubes and rods, for instance, cannot be added during the green stage and necessitate post-firing machining.
Sintering is a crucial stage in ceramic production that hardens the material but can also lead to shrinkage and warping. These issues often require corrective machining to achieve the desired tolerances. Additionally, ceramic parts and components, particularly those for technical applications, may have complex and intricate design features that can only be created through post-sintering machining.
How is Ceramic Machining Performed?
Ceramic machining involves processes such as milling, drilling, grinding, and turning, applied to ceramics that have been fired to their full density. While these methods are similar to those used in metal machining, ceramics' greater hardness and density necessitate cutting tools with exceptional strength and durability to handle the material effectively.
Machining green ceramic components is typically done with traditional tools, such as those made from steel, carbon steel, or stainless steel, due to the material's properties. However, parts that require highly precise shaping are often machined after the ceramics have been fully fired, rather than during the green ceramic stage.
Making Ceramics
Ceramic machining starts with the initial manufacturing of ceramic parts, components, and products. This process traces back to one of the world’s oldest industries, which began with the shaping and forming of clay for utensils, bowls, and household items. Over the centuries, ceramics have evolved into a crucial element in numerous industrial applications. The production of ceramic components involves several stages, beginning with the processing of raw clay material.
Mixing
Mixing is the initial step where ceramic ingredients are combined with water or other chemicals to create slurries. Following this, the forming process shapes the base material using methods such as slip casting, extrusion, injection molding, or pressing for dry powders. This stage is crucial as it establishes the basic shape of the ceramic component.
Sintering
Sintering or firing is used to dry and solidify the ceramic piece. The formed clay is hardened at temperatures up to 1832 °F (1000 °C). During sintering, the molecules of the clay melt, but the shape of the clay does not decompose. Sintering is completed in two steps, which are bisque firing and glaze firing.
Bisque Firing - With bisque firing, items are heated in a kiln until they turn glass-like. The temperature rises slowly to remove any water remaining in the material. At 662°F (350°C), the water molecules vaporize. At 932°F (500°C), all the water is gone, leaving the clay dehydrated and changed into hard ceramic material.
Bisque firing continues up to 1742°F (950°C) until the clay becomes less fragile but is still porous enough to accept glazes. Once sintering is completed, the ceramic is allowed to slowly cool to avoid breakage due to rapid temperature changes, and it becomes bisqueware.
Glaze Firing - In glaze firing, a coating is applied to the bisqueware to color it, decorate it, or improve its properties. The kiln is slowly heated to the required temperatures to apply the glaze and slowly cooled.
Considerations in Ceramic Machining
Challenges may arise during ceramic manufacturing and machining processes. This section outlines common difficulties and provides solutions to facilitate and improve the ceramic machining process.
Deformation in Ceramic Products
One of the most common and detrimental defects in the ceramic industry is the unintended alteration of the product, often resulting from improper kiln-drying techniques. Deformation can also occur due to rapid temperature changes during the firing process, whether from heating or cooling the kiln too quickly. Therefore, careful monitoring of temperature control is essential to prevent such issues.
Cracking in Ceramic Products
Rapid temperature changes can lead to surface cracks in the ceramic product, resulting in uneven shrinkage both internally and externally.
Foaming in Ceramic Products
Foaming occurs when inadequate oxidation during the porcelain tile's decomposition causes the glaze to form bubbles. In billet glaze, foaming is typically caused by sulfate and organic impurities.
Chapter 2: What Are The Ceramic Machining Methods?
The production of ceramics results in a variety of parts, products, and components with diverse sizes, shapes, and strengths. Machining represents the largest cost in ceramic manufacturing, accounting for 50% to 90% of a part’s total cost. The efficiency of ceramic machining is assessed by the material removal rate (MRR), which measures the amount of material removed from a surface per minute.
There are two types of machining, each tailored to the specific needs of the ceramics being processed. Machining dense ceramics requires more robust and durable tools compared to those used for green ceramics. Additionally, the timing of the machining process differs: green ceramics are machined before they are fully hardened, while dense ceramics are machined as the final step in the manufacturing process.
Abrasive Machining
Abrasive machining can replace large chip machining techniques like milling, planing, broaching, and turning. It offers superior surface quality and accuracy compared to these traditional methods and produces minimal burrs. Abrasive machining is particularly effective for hard-to-machine materials, such as dense ceramics.
Grinding Process
Grinding encompasses several methods, including reciprocating, internal, external, centerless, and creep feed. This process uses a rotating abrasive wheel to remove material from the workpiece's surface. The grinding zone is continuously flushed with coolant, which cools and lubricates the contact area. As the coolant flows over the grinding zone, it helps remove microchips and debris generated during grinding.
Abrasive materials used for ceramics include diamonds and cubic boron nitride (CBN), each available in various grit sizes. Diamonds are commonly preferred for their hardness, though they wear out faster than CBN. CBN, while not as hard as diamonds, tends to be more durable. Both materials are embedded in a resin to enhance their effectiveness.
Honing Process
Honing employs fixed abrasives, with diamond being the preferred choice for ceramics. Unlike grinding, honing operates at slower speeds. It is primarily used to correct dimensional tolerance issues and is most commonly applied to polish internal cylindrical surfaces, such as the cylinder walls of car engines.
Applications such as these can be fully automated, allowing complete control over each step of the process, including automatic part dimension gauging. Honing is also employed to finish external surfaces, such as the outer surfaces of ball and roller bearing races, valves, and gear teeth. Because honing operates at lower speeds, it generates less heat compared to grinding, which minimizes damage and distortion to the workpiece from heating. This reduced heating also lowers the need for cooling, although maintaining adequate lubricity still requires the use of chemicals. Unlike grinding, there have been few significant efforts to develop honing fluids specifically for use with advanced ceramics.
Ultrasonic Machining Process
Applications such as these can be fully automated, allowing complete control over each step of the process, including automatic part dimension gauging. Honing is also employed to finish external surfaces, such as the outer surfaces of ball and roller bearing races, valves, and gear teeth. Because honing operates at lower speeds, it generates less heat compared to grinding, which minimizes damage and distortion to the workpiece from heating. This reduced heating also lowers the need for cooling, although maintaining adequate lubricity still requires the use of chemicals. Unlike grinding, there have been few significant efforts to develop honing fluids specifically for use with advanced ceramics.
The vibration decreases friction, helps limit fluid access, and facilitates the removal of swarf, ultimately leading to an increased machining rate. The tools generally have a diameter of up to 50 mm. In rotating ultrasonic machining, small grinding and thread-cutting wheels, as well as core and solid drills, are commonly used. It’s important to consider cutting fluids, bonding and abrasive properties, and the influence of grinding parameters equally in this process. Consequently, improvements in ceramic grinding techniques should be applicable to rotary ultrasonic machining.
In ultrasonic impact machining, the tool itself does not contain abrasive materials or come into direct contact with the workpiece. Instead, this technique uses an abrasive slurry circulated between the vibrating tool and the workpiece. The tool vibrates the fluid and abrasive particles, which then strike the workpiece, causing indentation and fracture that result in material removal. The distance between the workpiece and the vibrating tool greatly affects the removal rate. Ultrasonic impact grinding is a widely used method for machining advanced ceramics, ranking just behind grinding. Increased vibration frequencies and specialized fluids may enhance machining speed in ultrasonic impact grinding.
Lapping and Polishing Process
Lapping, like honing, is primarily a finishing process applied to objects that have been machined close to their final dimensions. Unlike honing, however, lapping utilizes a loose or free abrasive method. In lapping, the workpiece is pressed against a rigid surface, often cast iron coated with a slurry of abrasive particles. Some of these particles become embedded in the lapping tool’s surface and cut into the workpiece, while others roll between the two surfaces, contributing to the material removal process.
Lapping and polishing are sometimes viewed as distinct processes, though this is not always accurate. Lapping employs a rigid, firm surface to achieve precise tolerances, remove damage, and improve surface smoothness. Polishing, on the other hand, uses a softer, more flexible surface primarily to repair damage and produce an exceptionally smooth finish.
Liquid Abrasive Jet-Cutting Process
Liquid jet systems are primarily used for cutting rather than shaping or surface finishing. This technique is frequently employed for porous materials, which can be cut at very high rates. However, liquid jet cutting is less effective on advanced ceramics due to their hardness and density, resulting in significantly lower cutting rates.
The application of liquid jet cutting to modern ceramics has been facilitated by incorporating abrasive grit into the fluid stream. This technique merges localized fracture from liquid cavitation with slurry erosion for material removal. However, the addition of abrasive particles can lead to different types of machine damage. Consequently, the liquid abrasive jet process is not ideal for components that require precise tolerances and high surface quality.
Non-Abrasive Machining
Some of the non-abrasive machining methods include:
Electrical Discharge Machining (EDM)
Electrical energy can also be used for ceramic machining. This is known as electrical discharge machining (EDM) and has found many applications for advanced ceramic machining in the past years. EDM requires the ceramic workpieces to have an electrical resistivity of less than 100Ω-cm. This implies that Electrical Discharge Machining cannot be used for machining glasses and some ceramics.
EDM has proven effective on materials such as silicon-infiltrated silicon carbide, siliconized silicon carbide, and hot-pressed silicon carbide. To broaden EDM's application to other ceramics, their resistivity must be reduced to fall within the required range. However, it remains uncertain whether EDM qualifies as a low-damage machining method, as it often leaves a surface layer with melted or heat-affected material that contains high levels of residual stress and numerous microcracks.
Laser Beam Cutting
Focused laser beams are extensively used for the precise cutting of various materials, including metal, wood, and ceramics. Innovative methods, such as intersecting two laser beams within the workpiece, have been developed to cut blind kerfs. This technique employs specific cutting geometries, particularly when removing certain sections of the workpiece is necessary.
Friction Cutting and Microwave Cutting Processes
Friction cutting involves using a circular blade rotating at a speed that generates more heat than the material being cut. In this process, materials like alumina and silicon nitride are sliced into small slots with a spinning mild steel disk, which is then cooled with water. The microwave cutting process, on the other hand, involves localized heating of sintered alumina with microwaves. This technique causes local melting and an explosive discharge of molten material from beneath the surface when a wafer of sintered alumina is penetrated. While these methods are effective for cutting and slicing tasks, they are generally unsuitable for creating contoured surfaces with tight tolerances.
Combined Methods
Some of the combined methods include:
Thermally-Assisted Turning Process
Some engineered ceramics claim to operate well when heated with a plasma torch while being turned. The workpiece material is heated up to a maximum temperature of 1000°C using this technique before being cut using a polycrystalline diamond compact (PDC) or CBN cutting tool. Where machinability is enhanced, it is due to a change in the deformation and removal processes from more rigid to more plastic ones at the higher temperature.
Despite an eightfold reduction in tool wear when turning silicon nitride, the wear level remains excessively high. Heating materials prone to thermal shock, such as alumina and zirconia, with a plasma torch does not significantly improve machinability. Engineers can enhance the pliability of ceramic materials by initially heating them with a laser and then cutting them with a diamond tool. However, due to limited tool life and inadequate surface smoothness, thermally assisted turning is not well-suited for high-volume production.
Mechanical-Electrical Discharge
Recent advancements have made it possible to integrate electrical discharge with ultrasonic machining techniques. Through extensive experimentation, engineers have determined how to use metal-bonded diamond tools to process titanium diboride effectively. Under specific conditions, this method achieves higher material removal rates and a removal ratio of 110 (workpiece loss to wheel loss). However, further investigation is needed to assess whether this technology can be applied to other materials with sufficient conductivity for EDM.
Chemical-Electrical Discharge
Some engineers described chemical-electrical discharge as combining electrochemical reactions in an electrolyte with wire electrical discharge machining. This technique is used on silicon carbide, non-conducting glass, alumina, and silicon nitride specimens that are submerged in an appropriate electrolyte solution to allow for conduction.
This technique allows for efficient cutting of surface contours without direct contact between the tool and the workpiece. Reports indicate that ceramics can be cut at rates ranging from 0.12 to 0.14 mm/min. However, further research is needed to determine the feasibility of this technology for mass-producing advanced ceramics.
Green Ceramic Machining (GCM)
Green ceramic machining is a cost-effective method that conserves tools while shaping ceramic parts. This process occurs before the sintering stage, when the ceramic shape is held together by a binder that affects the material's strength and plasticity. During green ceramic machining, the ceramics are pressed and shaped with high-density packing to achieve precise forms and accurate dimensions.
Unlike dense ceramics, green ceramics can be machined with the same tools used for shaping metals. Although the material's particles may cause some wear on the tools, it is less severe compared to dense fired ceramics. Diamond tools are not necessary due to the material's plasticity. Green ceramics can be machined using standard processes such as turning, milling, grinding, and drilling. However, the depth of cuts must be carefully controlled with wear plates, and feed rates need to be managed. Additionally, the location of machining on the workpiece can affect the process speed.
Green ceramic machining is employed to create complex and multidimensional features on a workpiece that would be difficult to achieve after the sintering and firing processes. In some cases, machining after sintering can be time-consuming and costly, resulting in long production runs. This makes green ceramic machining a more appealing option.
Guidelines for Machining Ceramics
When deciding to machine ceramics, several considerations must be taken into account. Ceramics are strong, durable, and malleable, making them suitable for a wide range of applications. While their properties contribute to their widespread use, there are important factors that users need to be aware of before machining ceramics.
The choice of method for machining ceramics has to fit the type of ceramic since the various types react differently to certain machining procedures. Mullite is suited for laser cutting while zirconia, a delicate ceramic, is cut and molded using abrasive methods. Knowledge of the ceramic material can assist in matching the material to the proper tool.
As with all manufacturing processes, prototyping is essential for ceramic parts, particularly for complex and intricately designed components. After creating a prototype, it should be thoroughly tested and evaluated before proceeding with larger production runs. The prototype allows for design adjustments and refinements before scaling up production.
While machining ceramic parts shares similarities with machining other materials, there are specific guidelines for ceramics that should be followed during the design phase. These include:
No pointy edges
Make oval designs round
Sharp corners and edges increase the risk of breakage
Corner pockets are an alternative to sharp corners
Holes and slots should be spaced and not in close proximity
Results of Incorrect or Improper Machining of Ceramics
Despite their strength, hardness, and other beneficial properties, ceramic materials can lose their integrity and become defective if machined improperly. Issues such as ragged cutting or uneven, deformed edges can compromise the rigidity of ceramics. Machining is intended to refine ceramic parts to meet precise tolerances and design parameters. Any minor oversight in this process can lead to material failure.
Ceramic tubes might appear to be a minor component of a mechanism, but if they are not machined to precise dimensions, they can lead to significant damage and safety hazards. This also applies to geometric shapes that must be machined to exact tolerances to fit correctly into a finished design.
A crucial part of machining involves addressing errors or defects from the firing process, such as shrinkage and warping. The machining process corrects and removes these imperfections to ensure that the ceramic part meets the required tolerances. To achieve the best results and ensure the quality of the final product, the machining process must be carried out with the utmost precision.
The most significant failure in ceramic machining is the development of microcracks and fractures, which can result from improper use of machining tools or the selection of unsuitable tools. Ceramics are very brittle and highly susceptible to damage from cracks. Given the prevalence of this issue in ceramic manufacturing, manufacturers take great care to inspect finished products thoroughly, often using bright light or piezoelectric inspection methods.
Chapter 3: Who Are The Leading Ceramic Machine Manufacturers?
Ceramic machining is indeed a complex process. Fortunately, many manufacturers of ceramic machining equipment have refined this process to a high degree. This chapter will focus on prominent manufacturers of ceramic molding machines, highlighting the unique features of their leading equipment available in the United States and Canada.
Haas Automation:
Model: DT-1
Unique Features:
High-speed drilling and tapping capabilities.
Compact footprint suitable for small workshop spaces.
20-station automatic tool changer for efficient tool changes.
High-performance spindle for precision machining.
DMG Mori:
Model: DMU 50
Unique Features:
5-axis simultaneous machining for complex ceramic parts.
Integrated rotary table for multi-sided machining.
High rigidity and precision for optimal surface finishes.
Intelligent control system for efficient operation.
Makino:
Model: T1
Unique Features:
Thermal stability and rigidity for high-accuracy machining.
Advanced technologies for reducing cycle times.
High-speed spindle for efficient ceramic cutting.
User-friendly interface and programming capabilities.
Okuma:
Model: GENOS M460V-5AX
Unique Features:
5-axis simultaneous machining for complex ceramic geometries.
Powerful spindle for high material removal rates.
Thermo-friendly structure to minimize thermal distortion.
Intelligent machine control for enhanced productivity.
FANUC:
Model: Robodrill D21MiB5
Unique Features:
Compact and versatile machine for ceramic machining.
High-speed spindle for efficient cutting and drilling.
Easy integration with automation systems.
FANUC CNC control for precision and reliability.
Please note that the availability of specific models may vary over time, so it's always recommended to check with the manufacturers for the most up-to-date information and to determine the best machine for your specific ceramic machining needs.
Leading Manufacturers and Suppliers
Chapter 4: What Are The Categories and Types of Ceramics?
This chapter will discuss the types of ceramics based on their categories.
Pottery Ceramics
The terms "pottery" and "ceramic" both describe items made from clay that has been fired to hardness and then decorated or glazed. Clay is formed from naturally weathered rock and is a valuable material for creating dinnerware due to its pliability, flexibility, and ability to solidify permanently when baked at high temperatures. There are three main types of ceramic and pottery materials: porcelain, stoneware, and earthenware.
Earthenware
Potters have fired earthenware in ovens for countless years. When the Roman Empire was at its height, ceramics were employed as amphorae to ship wine and olive oil to the furthest reaches of the realm. However, liquids may leak through these containers, allowing goods like oil to go rancid after repeated use for an extended period. Earthenware, however, can be fired at lower temperatures than other conventional ceramics like stoneware and porcelain, reaching as low as 1200 °F (648 °C).
Some earthenware potters apply a varnish to their pieces to seal in moisture. However, due to the lower firing temperature, these pieces can still be scratched or damaged with a knife. Today, earthenware is commonly used for terracotta planters, various kitchenware, and many construction bricks. It is a popular choice for beginner potters because of its ease of use. Although earthenware is less flexible and more fragile compared to other types of pottery, its workability makes it appealing.
Porcelain
The popularity of porcelain increased in Europe and North America in the 1700s, making it the last type of pottery to reach the West. It has been prized for its toughness and durability in China for long before that point. In the past, porcelain was fired at temperatures considerably higher than stoneware. Typically, the final firing temperature was in the range of 2600 °F (1426 °C).
The primary distinction between stoneware and porcelain today is that porcelain is usually made from white clay. While various white clays or bone ash can be used, kaolin—known for its white mineral content—is most commonly employed for porcelain. However, kaolin is less forgiving and more challenging to work with compared to other clays, and it is more susceptible to damage in contemporary settings.
Sculptors can carve porcelain into more intricate shapes than they can with stone or earthenware. Since the 18th century, porcelain has been highly valued by collectors and has been used to depict detailed forms, from a horse’s flowing mane to the folds of a robe. For modern potters, the distinctions between porcelain and stoneware are becoming less clear as new technologies and techniques emerge.
Stoneware
Stoneware came into production after the invention of earthenware. Compared to earthenware, it takes a long time to fire. Most stoneware is fired at temperatures between 2000°F and 2400° F (1093 and 1315 °C), which is hotter than volcanic lava. Stoneware is vitrified at these extremely high temperatures, turning the exterior glazes into glass. Stoneware can currently be produced using a variety of clay shades, unlike porcelain, which is now almost exclusively white. Additionally, some stoneware has different clay colors blended in for a distinctive twist.
Stoneware offers several advantages over traditional ceramics; it is strong, durable, and nonporous. Its robustness, stylish appearance, and versatility make it suitable for a range of uses, from custom trophies to baking dishes. Under appropriate conditions, stoneware can withstand heat from microwaves, dishwashers, and ovens. Additionally, it retains and distributes heat more evenly than other materials, making it ideal for serving coffee and tea.
Sanitary equipment such as sinks and baths is commonly made from stoneware. It is also used in the chemical industry to produce components like pumps, valves, absorption towers, drainage pipes, underground cable sheaths, sewer pipes, and residential pipes. Although stoneware is more cost-effective than many other building materials, it is prone to fragility and tends to have limited market value if damaged.
Advanced Ceramics
Some advanced ceramics include:
Fire Bricks
Bricks are a common type of ceramic, typically made by heating materials similar to clay, such as sand. This type of ceramic is prevalent in many homes and exhibits a variety of properties depending on the manufacturing process. Bricks are known for their durability, weight, and ability to withstand high temperatures. Fire bricks, in particular, are used in chimneys, fireplaces, and walls due to these qualities. They are also frequently utilized in landscaping for their robust characteristics.
Tungsten Carbides
Tungsten carbide is a thick and durable material composed of the same amounts of carbon and tungsten. These ceramics are strong, thick, hard, long-lasting, and exhibit little electrical resistance. Because of these qualities, many items are made from this material ranging from various cutting tools to golf clubs.
Bone China
By adding powdered bone ash to the standard ceramics formula, ceramicists developed a less brittle type of porcelain called bone china. This variation not only retained the traditional ivory-white appearance of porcelain but also offered improved durability. Today, bone china has largely replaced pure porcelain in many applications and is often regarded as a stronger form of porcelain.
Bone china is inherently colorless or white, while unfired porcelain clay can appear cream or white. Bone china undergoes a two-stage firing process. The first stage, known as bisque firing, transforms the material into a translucent, glass-like form. The second stage, glaze firing, occurs at a lower temperature and melts the material into detailed shapes with a protective coating.
The shell of bone china is highly durable and provides strong resistance to chipping and wear. This strength is due to the presence of materials such as feldspar, kaolin, phosphates, and quartz.
Glass Ceramics
Glass ceramics are a type of ceramic that combines the properties of glass with the strength and hardness typical of ceramics, achieved through controlled crystallization. Modern manufacturing techniques produce these materials with several desirable attributes, including zero porosity, mechanical strength, durability, high temperature resistance, transparency, and biocompatibility.
Glass ceramics exhibit exceptional superconductivity and chemical resistance. They are commonly used in cookware, bakeware, and stovetop accessories. Additionally, glass ceramics are frequently employed in industrial, scientific, and medical equipment.
Silicon
Silicon is another widely recognized ceramic material known for its superior chemical properties. It is abundant, comprising about 90% of the Earth's crust, and is commonly found in the clays used to create traditional pottery. For example, silicate minerals such as kaolinite and silica are used to produce porcelain and fired bricks, respectively.
Silicon is the material of choice for manufacturing semiconductors due to its atomic bonding capabilities, strength, and abundance. Crystalline silicon, closely related to polycrystalline silicon, is used to produce ultra-pure semiconductors for applications such as integrated circuits and solar panels. High-quality silicon minerals are also essential in the production of cement aggregate, glass, and ceramics. As a result, silicon is one of the most widely used raw materials in the construction industry.
Silicon Carbide
Silicon carbide is another type of ceramic material, renowned for its superior semiconductor properties due to its composition of silicon and carbon. It naturally occurs as the rare mineral moissanite. Silicon carbide ceramics are both strong and exceptionally hard. There are approximately 250 different crystalline forms of this semiconductor.
Although this porcelain is naturally white, additional substances, like iron, sometimes color it. It also exhibits a low thermal conductivity. Examples of applications for this ceramic include cutting tools, furnaces, braking discs, abrasives, heating elements, lights, and electrical power systems. The natural form of silicon carbide is prized as a jewel because it resembles diamonds in appearance and toughness. It is a more durable substitute for synthetic zirconia.
Silicon Nitride
Silicon nitride, composed of silicon and nitrogen (Si₃N₄), is a high-performance ceramic known for its exceptional strength, toughness, hardness, and excellent chemical and thermal stability. The properties and applications of silicon nitride ceramics vary based on their fabrication methods, leading to five distinct types.
The five types of silicon nitride are:
Reaction Bonded (RBSN) – RBSN is made by nitriding a silicon compact at 2642 °F (1450 °C), during which the silicon nitride grows in the porosity of the compact. The result is an increase in the ceramic’s density, making it ideal for producing net-shaped parts.
Hot Pressed (HPSN) – HPSN is used to produce cutting tools. It must be diamond-cut due to its density and hardness, which makes its parts more expensive.
Sintered Reaction Bonded (SRBSN) – SRBSN is a new form of RBSN. It has been designed to remove the porosity of RBSN and improve its mechanical properties. SRBSN has exceptional toughness and impact resistance.
Gas Pressure Sintered (GPSN) – GPSN uses gas pressure and heat of around 3632 °F (2000 °C) to inhibit pyrolysis of silicon nitride and promote silicon nitride grain growth. The result is a ceramic with high toughness and a density of >99%. GPSN is strong and wear-resistant, with good process performance.
Sintered (SSN) – The SSN process takes silicon nitride ceramic material and densifies it with pressureless sintering in a nitrogen atmosphere. Different combinations of additives are used to help in the densification to make a ceramic with excellent mechanical properties.
Titanium Carbide
Titanium carbide is a ceramic material known for its strength, heat resistance, and dark coloration. It is highly durable, wear-resistant, heat-resistant, and corrosion-resistant. This material is commonly used in watch movements, heat shields, machine parts, and tool bits.
Boron Carbide
Boron carbide ceramics, composed of boron and carbon, are among the hardest known materials. With a Mohs hardness rating between 9.5 and 9.75, boron carbide is extremely hard. It also resists chemical reactions and offers effective shielding against neutrons.
Often referred to as "black diamond," boron carbide is recognized as a p-type semiconductor. Its exceptional hardness ensures excellent wear resistance. Additionally, boron carbide's strong mechanical properties and low specific gravity make it ideal for manufacturing lightweight armor.
Boron carbide is produced using fusion with carbon or by a magnesiothermic reaction. It can also be manufactured using pressureless sintering at temperatures of 4172 to 4352 °F (2300 to 2400 °C) using various sintering aids.
Structural Ceramics
Structural ceramics are typically made from clay and molded into the desired shape. Their insulating properties can be adjusted by varying their density—higher density results in reduced insulation. Examples of structural ceramics include bricks, dinnerware, and statues.
Refractory Ceramics
Refractory ceramics retain their strength and shape even at extremely high temperatures, making them ideal for use in furnaces and kilns. They are made from various oxides, such as zinc oxide, titanium dioxide, and silicon dioxide.
Electrical Ceramics
Electrical ceramics, also known as electroceramics, are distinguished by their exceptional electrical properties. They are valuable for a range of applications due to their strong mechanical, thermal, and electrical characteristics. These ceramics become more conductive as temperatures increase. Examples include ceramic rapid ion conductors and dielectric ceramics.
Magnetic Ceramics
Magnetic ceramics, also known as ferrites, are oxide materials characterized by permanent magnetic properties, specifically ferrimagnetism. They are composed of iron oxide combined with another metal. Magnetic ceramics are used in a variety of applications, including transformers, telecommunications, and data storage.
Abrasive Ceramics
Ceramic abrasives, used for cutting or grinding softer materials, can be either natural or synthetic. They are known for their durability, wear resistance, and hardness. Among these, diamond is the most notable abrasive ceramic.
Comparison of Metal to Ceramics
A metal is defined as a material that occurs naturally or is created through manufacturing processes. Metals are typically shiny, ductile, and malleable, and they are found in the Earth's crust. They can exist in pure form or within rocks and ores from which they are extracted. The appeal of metals lies in their ability to be shaped and formed into a wide range of products.
Ceramics are non-metallic inorganic materials composed of non-metallic compounds that can be shaped and hardened. They are characterized by their brittleness, corrosion resistance, and exceptional hardness. Made from a mixture of clay, various elements, powders, and water, ceramics are bound with a binder and molded into products, parts, and components.
Comparison of the Properties of Ceramics and Metals
Ceramics
Metals
Electrical and thermal insulators
Conductors of heat and electricity
Harder than metals
Ductile and malleable
Used to cut metals
Have a variety of melting points
Dull or matte
Shining with a luster
Covalent bonds
Metallic bonds
Will not bend
Easily bent and shaped
Made up of nonmetallic materials
Composed of multiple elements
Brittle and fracture easily
Denser
Chapter 5: Advantages, Disadvantages and Applications of Ceramics in Ceramic Machining
This chapter will discuss the applications, benefits, and disadvantages of ceramics as used in ceramic machining.
Advantages of Ceramics in Ceramic Machining
They are frequently used as cutting tools and abrasive powder due to their extreme hardness.
Due to their high melting point, they are perfect for use as refractory materials.
They are also effective thermal insulators, which is another reason to use them as refractory materials.
Due to their high electrical resistance, they are perfect for use as insulators.
Their low mass density allows them to make lightweight ceramic components.
They typically resist corrosion because they are already oxidized due to the special formation of their chemical bonds.
They are cost-effective since they are readily available.
Glazed ceramic material is durable and resists stains.
Disadvantages of Ceramics in Ceramic Machining
They are not particularly stretchy.
They lack significant tensile strength.
There is a wide range of strength variance, even with similar specimens.
They are challenging to create and form.
Their dimensional tolerances are challenging to maintain throughout processing.
Ceramic products exhibit poor shock resistance causing them to break when impacted.
They have a low friction coefficient, allowing other materials to slide easily off them.
Applications of Ceramics in Ceramic Machining
Due to their great abrasion resistance, technical ceramics like silicon carbide and tungsten carbide are utilized in body armor, mining wear plates, and machine components.
A ceramic called uranium oxide (UO2) is utilized as fuel for nuclear reactors.
Zirconia is a type of ceramic used to create oxygen sensors, fuel cells, jewels, and ceramic knife blades.
A ceramic called barium titanate is used to create transducers, capacitors, heating elements, and data storage components.
Another ceramic called steatite is employed as an electrical insulator.
The Difficulties of Machining Ceramics
Machining ceramics presents several challenges due to their inherent properties. Their high hardness, brittleness, and resistance to machining make the process difficult. Conventional machining techniques often fail because they rely on chip formation through shearing, which can cause breakage in the brittle structure of ceramics.
Machining ceramics is a precise process that demands careful control, attention to detail, and skilled craftsmanship. Many manufacturers now prefer CNC machining for ceramics to overcome the challenges associated with manual techniques. The brittleness of ceramic materials can lead to the development of microcracks and fissures during machining, which can render the product defective.
Machining ceramics can result in surface damage, edge chipping, and pitting. Ensuring dimensional accuracy and minimizing collateral damage, such as surface cracks, necessitates careful monitoring of the machining process.
Conclusion
Ceramic materials that are mixed, shaped, and formed are utilized to create industrial and commercial parts and components. Machining plays a crucial role in their production by refining the features and tolerances of ceramic items. Similar to machining metal parts, the machining process for ceramics involves removing portions of the surface to modify the size and shape of the ceramic piece.
Unlike metal machining, ceramics require specialized tools capable of matching their hardness, strength, and toughness. Due to their density and hardness, ceramics demand extensive, precise machining processes, including drilling, turning, grinding, and milling.
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